ChemInform Abstract: Reductive Alkylation of Bis(triflyl)methane Through Self-Promoting Formation of Easily Isolable 1,1-Bis(triflyl)alkenes

Autor:	Saki Egawa, Takeo Taguchi, Hikaru Yanai
Rok vydání:	2013
Předmět:	Alkane chemistry.chemical_classification chemistry.chemical_compound Chemistry Acetal Condensation Organic chemistry General Medicine Alkylation Brønsted–Lowry acid–base theory Alkadienes Methane Catalysis
Zdroj:	ChemInform. 44
ISSN:	0931-7597
Popis:	A convenient and practical synthesis of 1,1-bis(triflyl)alkenes via self-promoting condensation of Tf2CH2 and aldehydes was developed and chemical behavior of these alkenes was investigated. Among the alkenes, easily isolable 1,1-bis(triflyl)alkadienes derived from α,β-unsaturated aldehydes could be used as useful building blocks for 1,1-bis(triflyl)alkanes. The 1,1-bis(triflyl)alkane thus obtained showed catalyst activity in the acetal forming reaction, which is a typical reaction catalyzed by Bronsted acids.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2071f0f3794a38f43238c6369e4b9824 https://doi.org/10.1002/chin.201331052 Zobrazit plný text záznamu Plný text