Vibronic state and optical spectrum of the N i2+ impurity ion in CaO

Autor:	A. V. Lushnikov, V. I. Cherepanov, S. Yu. Shashkin
Rok vydání:	1999
Předmět:	Physics Dipole Impurity Magnetic circular dichroism General Physics and Astronomy Vibronic spectroscopy Physics::Chemical Physics Atomic physics Polarization (waves) Visible spectrum Ion Magnetic field
Zdroj:	Russian Physics Journal. 42:528-532
ISSN:	1573-9228 1064-8887
DOI:	10.1007/bf02508268
Popis:	The relative intensities of vibronic splitting components of the3A2g→1T2g optical electronic dipole transition induced by odd local vibrations and spin-orbit interaction are calculated for an impurity center with O h point-group symmetry. The polarization dependences and magnetic circular dichroism (MCD) are found for the vibronic components in an external magnetic field. In contrast with the previous works, the calculation is not confined to the nearest-term approximation. It is shown that measurements of the polarization dependences and MCD allow one to identify unambiguously the vibronic components. A comparison with the experiment is carried out for theNi 2+ ion in CaO.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::204cf531513966068a77c4d1b0e80962 https://doi.org/10.1007/bf02508268 Zobrazit plný text záznamu Full text from SpringerLink