Oxydation des alcools. I - Choix de l'adamantanol pour déterminer la structure de l'état de transition dans l'oxydation par Cr(VI)

Autor:	Patrick Geneste, R. Durand, J.P. Roque, Gérard Lamaty
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Bicyclic molecule Stereochemistry General Chemistry Nonane Cis–trans isomerism
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 94:131-134
ISSN:	0165-0513
Popis:	The comparison of the rates of chromic oxydation of 2-adamantanol, bicyclo[3.3.1]nonan-9-ol and cis and trans 4-tert-butylcyclohexanols shows that the transition state of this reaction is product-like. It appears that 1,3 diaxial interactions increase, according to the system, in the following order: cyclohexyl < adamantyl < bicyclo[3.3.1]nonane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::204af20d7bff7fb29cd4e5cc94ce024e https://doi.org/10.1002/recl.19750940607 Zobrazit plný text záznamu