Electrochemical Synthesis, Properties, and Structure of 1,10-Phenanthroline Adducts of Mononuclear Copper, Cobalt, and Nickel Chelates in the N,N,O-Ligand Environment
| Autor: | Anatolii S. Burlov, Ali I. Uraev, Nadezhda I. Makarova, Sergey I. Levchenkov, Yu. V. Koshchienko, Dmitrii A. Garnovskii, G. G. Aleksandrov, Valery G. Vlasenko |
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| Rok vydání: | 2018 |
| Předmět: |
Schiff base
General Chemical Engineering Phenanthroline chemistry.chemical_element Infrared spectroscopy General Chemistry Zinc 010402 general chemistry 010403 inorganic & nuclear chemistry Electrosynthesis 01 natural sciences Copper 0104 chemical sciences chemistry.chemical_compound Nickel chemistry Polymer chemistry Cobalt |
| Zdroj: | Russian Journal of Coordination Chemistry. 44:596-603 |
| ISSN: | 1608-3318 1070-3284 |
| Popis: | 1,10-Phenanthroline (Phen) adducts [M(L)Phen] in copper(II), cobalt(II), and zinc(II) chelates based on N,N,O-tridentate tosylamino-functionalized pyrazole-containing Schiff base (H2L), resulting from condensation of 2-tosylaminoaniline with 3-methyl-1-phenyl-4-formylpyrazol-5-ol, were obtained by electrosynthesis. The composition and structure of the mixed-ligand complexes were confirmed by elemental analysis, IR spectroscopy, and magnetochemical measurements. The structures of azomethine H2L and mixed-ligand copper(II) complex were determined by X-ray diffraction. |
| Databáze: | OpenAIRE |
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