Photooxidation of Methane to Methanol by Perrhenate in Water under Ambient Conditions

Autor:	Horst Kunkely, Arnd Vogler
Rok vydání:	2013
Předmět:	chemistry.chemical_compound Perrhenate chemistry Inorganic chemistry Organic chemistry General Chemistry Methanol Methane Catalysis
Zdroj:	Zeitschrift für Naturforschung B. 68:891-894
ISSN:	1865-7117 0932-0776
DOI:	10.5560/znb.2013-3104
Popis:	The oxidation of methane to methanol takes place selectively by the photolysis of perrhenate in aqueous solution in the presence of methane. This photoreaction is formally an oxygen atom transfer. Because the reoxidation of the reduced perrhenate is accomplished with hydrogen peroxide the overall process can be viewed as photocatalytic oxidation of methane to methanol: CH4 + H2O2 → CH3OH+ H2O.
Databáze:	OpenAIRE
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