Attempts at asymmetric electrosynthesis of α-fluorinated cyclopropylphosphonamides

Autor:	Christian Feasson, Hassan Oulyadi, Philippe Jubault, Jean-Charles Quirion, Sophie Goumain
Rok vydání:	2001
Předmět:	Acrylate chemistry.chemical_compound Chemistry Organic chemistry Electrosynthesis
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :701-705
ISSN:	1364-5463 1472-7781
DOI:	10.1039/b008906k
Popis:	Variously N,N-disubstituted chiral dibromofluoromethylphosphonamides 3 were easily prepared and used for the asymmetric electrosynthesis, in the presence of tert-butyl acrylate, of α-fluorinated cyclopropylphosphonamides 7. The diastereoisomeric excesses are moderate (up to 40%). Moreover, the identification of the trans and cis stereoisomers has been deduced from analysis of 2D 1H–19F HOESY spectra.
Databáze:	OpenAIRE
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