Synthesis and characterization of two new bulky tris(mercaptoimidazolyl)borate ligands and their zinc and cadmium complexes

Autor:	Christopher D. Incarvito, Vinay K Bhatia, Daniel Rabinovich, Selma Bakbak, Arnold L. Rheingold
Rok vydání:	2001
Předmět:	Tris Cadmium Chemistry Electrospray ionization Inorganic chemistry chemistry.chemical_element Crystal structure Zinc Sodium salt Inorganic Chemistry chemistry.chemical_compound Yield (chemistry) Materials Chemistry Physical and Theoretical Chemistry Boron Nuclear chemistry
Zdroj:	Polyhedron. 20:3343-3348
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(01)00954-8
Popis:	The sodium salts of the tris(2-mercapto-1-benzylimidazolyl)borate [TmBz]− and tris(2-mercapto-1-p-tolylimidazolyl)borate [Tmp-Tol]− anions have been readily prepared in very good yield from NaBH4 and 2-mercapto-1-benzylimidazole or 2-mercapto-1-p-tolylimidazole, respectively. These new monoanionic tripodal sulfur-donor ligands have been used to prepare the Group 12 derivatives (TmR)MBr (M=Zn, Cd; R=Bz, p-Tol), all of which have been characterized by a combination of analytical and spectroscopic techniques, including electrospray ionization mass spectrometry (ESI MS) and, in the case of both benzyl-substituted derivatives, single-crystal X-ray diffraction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1ff89d632d0a1ed7e12f995969d671a2 https://doi.org/10.1016/s0277-5387(01)00954-8 Zobrazit plný text záznamu Full Text from ScienceDirect