Three new hybrid compounds constructed from {PSb2Mo12O40} polyoxoanions, TMMC or organic amines
| Autor: | Li-Hong He, Shu-Yun Shi, Jun Zhang, Ying Li, Ling-Yu Chen, Xiao-Bing Cui |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Hydrogen bond Carboxylic acid 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Decomposition 0104 chemical sciences Inorganic Chemistry Crystallography chemistry.chemical_compound Transition metal chemistry Pyridine Materials Chemistry Rhodamine B Photocatalysis Physical and Theoretical Chemistry 0210 nano-technology Single crystal |
| Zdroj: | Inorganic Chemistry Communications. 99:149-155 |
| ISSN: | 1387-7003 |
| DOI: | 10.1016/j.inoche.2018.11.005 |
| Popis: | Three new compounds {[Ni(biim)(dipic)(H2O)][PSb2IIIMo6VMo6VIO40]·(Hbiim)}·1.5H2O (1); [(HTEA)(TEA)0.75]2 [PSb2IIIMo5V Mo7VIO40](2), (TEA)]2[HPSb2IIIMo4VMo8VIO40](3) (dipic = 2, 6- pyridine carboxylic acid, biim = 2, 2-biimidazole, TEA = triethylamine) have been synthesized under mild hydrothermal condition and structurally characterized by physico-chemical and spectroscopic methods. Single crystal X-ray diffraction analysis reveals that compound 1 represents new example formed by {PSb2Mo12O40} and transition metal mixed-organic-ligand complexes (TMMCs). The compounds 1–3 all exhibit novel 3D supermolecular channel structures through complex hydrogen bonds and strong O┄O supermolecular interactions. The photocatalytic activities of compounds 1–3 for decomposition of rhodamine B (RhB) and methylene blue (MB) under UV irradiation have also been investigated. |
| Databáze: | OpenAIRE |
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