Use of Si KLL Auger shifts and the Auger parameter in XPS to distinguish Ti silicides from a Ti/Si mixture in thin films

Autor: Kuratomi Takashi, David Thompson, Paul Mack, I-Cheng Chen, Christopher R. Brundle, Ghazal Saheli, Christopher Lazik, Jeffrey W. Anthis
Rok vydání: 2019
Předmět:
Zdroj: Journal of Electron Spectroscopy and Related Phenomena. 234:57-63
ISSN: 0368-2048
DOI: 10.1016/j.elspec.2019.04.004
Popis: A particular wafer processing step involves deposition of a Ti thin film (˜6 nm to ˜13 nm) on Si, under processing conditions intended to form a silicide with specific electrical properties. It is difficult, however, to distinguish silicide formation from mere elemental inter-diffusion. Routine laboratory XPS, using an Al X-Ray source(1486.6ev), does have an appropriate probing depth for the film stack involved, but the chemical shifts in Ti (2p) and Si(2p) are too small (
Databáze: OpenAIRE