A GENERAL ROUTE TO TIN-NITROGEN HETEROCUBANES

Autor:	Oliver Just, William S. Rees, Jack F. Eichler
Rok vydání:	2004
Předmět:	Inorganic Chemistry chemistry.chemical_compound Zirconium Crystallography Chemistry Yield (chemistry) Dimer Organic Chemistry chemistry.chemical_element Tin Biochemistry Nitrogen Single crystal
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 179:715-726
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426500490426656
Popis:	The reaction of the lithiated bis-stannylamine, ((CH3)3)Sn2NLi·THF (1), with (C5H5)2ZrCl2 yields the imido-bridged zirconium dimer, [(C5H5)2ZrN(Sn(CH3)3)]2 (3), which was characterized by single crystal x-ray diffractometry. The heteroleptic stannylamine, [{(CH3)3Sn}{(CH3)3Si}]NLi·Et2O(2), prepared using(1)as a synthetic precursor, reacts with SnCl2 to yield the tin-nitrogen heterocubane, [Sn(μ3-NSi(CH3)3)]4 (4), which is fully characterized by single crystal x-ray diffractometry and standard spectroscopic techniques. The use of this class of stannylamine ligands allows access to heterometallic amido complexes and provides a general route to obtaining tin-nitrogen heterocubanes.
Databáze:	OpenAIRE
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