Efficient 1,2-asymmetric induction in radical reactions: Addition of acyl radicals to 3-hydroxy-1-(methylthio)-1-(p-tolylsulfonyl)-1-alkenes and their acetates

Autor:	Akio Kayano, Takayuki Arai, Motohiro Akazome, Katsuyuki Ogura
Rok vydání:	1999
Předmět:	chemistry.chemical_compound Chemistry Radical Organic Chemistry Drug Discovery Benzophenone Organic chemistry heterocyclic compounds Selectivity Biochemistry Asymmetric induction Medicinal chemistry
Zdroj:	Tetrahedron Letters. 40:2537-2540
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(99)00196-3
Popis:	Irradiation of aliphatic and aromatic aldehydes in the presence of benzophenone produces the corresponding acyl radicals which add to 3-hydroxy-1-(methylthio)-1-( p -tolylsulfonyl)-1-alkenes and their acetates with high syn selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f71f70cd248d7e7ece223e349e04327 https://doi.org/10.1016/s0040-4039(99)00196-3 Zobrazit plný text záznamu Full Text from ScienceDirect