Ferrocenophane-based bifunctional organocatalyst for highly enantioselective Michael reactions

Autor:	Ru Jiang, Wei Yao, Xiaowei Zhou, Jun-Chao Zhu, Weiping Chen, Ping-An Wang
Rok vydání:	2018
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry Acetylacetone Organic Chemistry Drug Discovery Enantioselective synthesis Organic chemistry 010402 general chemistry Bifunctional 01 natural sciences Biochemistry 0104 chemical sciences
Zdroj:	Tetrahedron. 74:4205-4210
ISSN:	0040-4020
DOI:	10.1016/j.tet.2018.06.036
Popis:	Highly enantioselective Michael reactions between acetylacetone and trans-β-nitroolefins are achieved by a novel ferrocenophane-based tertiary amine-thiourea organocatalyst to provide the corresponding products in good to excellent yields (up to 95%) and enantioselectivities (up to 99% ee).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f670cc6106b2de57f22b274269af457 https://doi.org/10.1016/j.tet.2018.06.036 Zobrazit plný text záznamu Full Text from ScienceDirect