Thermal behaviourof complexes of antipyrine derivatives Part III

Autor:	E. Pál, Imre Labádi, Ramona Tudose, Otilia Costisor
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Thiocyanate Inorganic chemistry chemistry.chemical_element Condensed Matter Physics Copper Perchlorate chemistry.chemical_compound Piperazine chemistry Organic reaction Polymerization Polymer chemistry Physical and Theoretical Chemistry Counterion Cobalt
Zdroj:	Journal of Thermal Analysis and Calorimetry. 83:681-686
ISSN:	1588-2926 1388-6150
Popis:	The thermal behaviour of the mixed-ligand complexes of cobalt(II) and copper(I) ions with antipyrine derivatives of 1,2-ethanediamine or piperazine (BAMP and TAMEN), with water and with 2-mercapto-benzothiazole (Hmbt) was investigated. The complexes contain 2-mercaptobenzothiazole (Hmbt, in the case of cobalt(II) ion) or dimercaptobenzothiazine (mbt–mbt, in the case of copper(I) ion) molecules as ligands and perchlorate (ClO4–) or thiocyanate (SCN – ) ion as counterion. By heating, water and ligands release the solid phase at lower temperature. At higher temperatures process of different organic reactions of ligands (e.g. polymerization, polycondensation) could be suggested to interpret the relative high final mass values.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f5ac4437785d1197a78abd00bb25da5 https://doi.org/10.1007/s10973-005-6990-3 Zobrazit plný text záznamu Plný text ve formátu PDF