Oxygen-contact charge transfer complexes in organic bicomponent systems
| Autor: | Weixiao Cao, Zhengping Liu, Xinde Feng, Junmin Zhu |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
Range (particle radiation)
Multidisciplinary Ethanol genetic structures Absorption spectroscopy Chemistry Component (thermodynamics) Analytical chemistry chemistry.chemical_element Oxygen eye diseases chemistry.chemical_compound Organic chemistry sense organs Absorption (chemistry) Benzene Dynamic equilibrium |
| Zdroj: | Chinese Science Bulletin. 43:1798-1802 |
| ISSN: | 1861-9541 1001-6538 |
| DOI: | 10.1007/bf02883375 |
| Popis: | The O2-CCT absorption spectra of bicomponent systems were measured. The influences of various organic compounds as well as the component concentration on the O2-CCT formation ability were investigated. The results show that if the difference of O2-CCT formation ability between the two components is rather large, such as the benzene/ isopropyl ether system, only the O2-CCT absorption of benzene appears, which arises from its higher O2-CCT formation ability. If the difference of O2-CCT formation ability is small, such as the isopropyl ether/ethanol system and the dioxane/isopropyl ether system, it is rather easy to form a dynamic equilibrium of two O2-CCT between the two components, then only one absorption peak appears in the whole concentration range as a result of the repeated addition of the two kinds of O2-CCT absorption. If the difference of O2-CCT formation ability is in medium compared with the two cases above, such as the dioxane/ethanol system, there are two kinds of2-CCT absorption of dioxane and ethanol in the same system in the form of an equilibrium, then two absorption peaks can be detected in the middle concentration range as a result of the repeated addition of the two kinds of2-CCT absorption. |
| Databáze: | OpenAIRE |
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