ChemInform Abstract: Enantioselective Synthesis of the Quinolizidine Alkaloids (+)-Myrtine and (-)-Epimyrtine

Autor:	Jean-Claude Gramain, Bertrand Perrin, Roland Remuson, D. Gardette, Yvonne Gelas-Mialhe
Rok vydání:	2010
Předmět:	Epimyrtine chemistry.chemical_compound Quinolizidine chemistry Stereochemistry Intramolecular force Enantioselective synthesis General Medicine
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199840250
Popis:	The enantioselective synthesis of (+)-myrtine 1 and (−)-epimyrtine 2 is described starting from ( S )-2-(2-hydroxypropyl)allyltrimethylsilane 4 using an intramolecular allylsilane N -acyliminium ion cyclization.
Databáze:	OpenAIRE
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