Methylmercuric halide-halide complexation in ethanol solution

Autor:	Peter R. Wells, Vittorio Lucchini
Rok vydání:	1975
Předmět:	Ethanol Chemical shift Organic Chemistry Inorganic chemistry Halide Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Stability constants of complexes Bromide Mole Materials Chemistry Composition (visual arts) Physical and Theoretical Chemistry
Zdroj:	Journal of Organometallic Chemistry. 92:283-290
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)85679-x
Popis:	The formation constants for CH3HgCl2− at 26°C (0.31 l/mole), and for CH3HgBr2− at 26°C (0.94 l/mole) and at 60°C (0.70 l/mole) in ethanol solution have been determined from the variation of Hg NMR chemical shift (by INDOR) with composition of methylmercuric halide-lithium halide solutions. These data have been employed in a reexamination of the “one-anion” and “two-anion” catalysed reactions of mercuric bromide with alkylmercuric bromides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f40bd009da6cb3303f71341be2beb6b https://doi.org/10.1016/s0022-328x(00)85679-x Zobrazit plný text záznamu