Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization

Autor:	Alexander A. Vinogradov, Ilya E. Nifant'ev, Pavel V. Ivchenko, Alexey A. Vinogradov
Rok vydání:	2021
Předmět:	chemistry.chemical_compound Chemistry Hydride Ethylene polymerization Fundamental difference Computational chemistry General Chemistry Triisobutylaluminium Catalysis Interpretation (model theory)
Zdroj:	Mendeleev Communications. 31:523-525
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2021.07.029
Popis:	DFT simulations of ethylene polymerization with the participation of neutral Zr–Al3 hydride species revealed a fundamental difference in catalytic behaviour of triisobutylaluminium-activated heterocenes and conventional ansa-zirconocenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f24d5b2a5486c419563c9cdaae539c9 https://doi.org/10.1016/j.mencom.2021.07.029 Zobrazit plný text záznamu Full Text from ScienceDirect