Low-temperature isomerization of n-butane to isobutane

Autor:	N. R. Bursian, N. K. Volnukhina, G. V. Stavrova, E. I. Zhemchugova
Rok vydání:	1969
Předmět:	Hydrogen General Chemical Engineering Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Butane General Chemistry Electrolyte Photochemistry Decomposition Catalysis chemistry.chemical_compound Fuel Technology chemistry Yield (chemistry) Isobutane Isomerization
Zdroj:	Chemistry and Technology of Fuels and Oils. 5:770-775
ISSN:	1573-8310 0009-3092
DOI:	10.1007/bf00719128
Popis:	1. A process has been developed for low-temperature isomerization of n-butane on an NIP-66 catalyst. 2. The process parameters have been studied and the conditions for effecting isomerization of n-butane selected. 3. The catalyst has been subjected to prolonged tests under the selected conditions; it exhibited satisfactorystability over a period of 2000 h. 4. The technological indices of the process based on electrolytic hydrogen and on hydrogen-containing reforming gas have been determined. At 200‡C, 20 atm, an n-butane feed rate of 1.0 h−1, and a 1∶1 molar ratio of hydrogen to n-butane, the isobutane yield was about 45 wt. %, which is about 80% of the equilibrium value. The yield of the decomposition products was 2.9 wt. % for electrolytic hydrogen and 4.3 wt. % for reforming gas.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1f1d556012041094efa9d5bb12c930a5 https://doi.org/10.1007/bf00719128 Zobrazit plný text záznamu Full text from SpringerLink