Synthesis, structure and characterization of binuclear silver(I) complexes

Autor:	Hou Yimin, Yang Ruina, Jin Douman, Wang Dongmei, Xue Bao-Yu
Rok vydání:	1996
Předmět:	Denticity Ligand Dimer Metal ions in aqueous solution Metals and Alloys chemistry.chemical_element Crystal structure Copper Catalysis Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Materials Chemistry Organometallic chemistry
Zdroj:	Transition Metal Chemistry. 21
ISSN:	1572-901X 0340-4285
DOI:	10.1007/bf00166008
Popis:	Two binuclear AgI complexes, [{Ag(dppp)}2](NO3)2 (1) and [{Ag(dppb)}2(NO3)]2 (2) (dppp = Ph2P(CH2)3PPh2, dppb = Ph2P(CH2)4PPh2], were synthesized and characterized by elemental analysis, t.g., i.r. and 31P-n.m.r. spectra. Single crystals of complex (2) were obtained from MeOH-CHCl3. The X-ray crystal structure shows that the dppb ligand is bidentate, with two ligands bridging two metal ions to form a centrosymmetric dimer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1ef2c4069d77520fdbafa257c2118e2b https://doi.org/10.1007/bf00166008 Zobrazit plný text záznamu Full text from SpringerLink