| Autor: |
Hans Vermeer, Armin Schweig, W. Schäfer, F.M. Bickelhaupt, C. Jongsma |
| Rok vydání: |
1975 |
| Předmět: |
|
| Zdroj: |
Tetrahedron. 31:2931-2935 |
| ISSN: |
0040-4020 |
| DOI: |
10.1016/0040-4020(75)80313-9 |
| Popis: |
The synthesis of 10-methyl-9-phosphaanthracene (1b) is described. Its stability is found to be intermediate between that of the unsubstituted parent compound (1a) and of the 10-phenyl derivative (1c). The electronic structure of this new phosphaaromatic system is studied, especially by photoelectron spectroscopy. As inductive and/or conjugative effects of the substituents are shown to be of minor importance, it is concluded that mainly steric effects stabilize the 9-phosphaanthracene system. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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