Reduction of phosphine oxides to the corresponding phosphine derivatives in Mg/Me3SiCl/DMI system

Autor:	Hiromu Kawakubo, Toshihito Kita, Toshimasa Katagiri, Syoko Yamane, Manabu Kuroboshi, Asuka Aono, Hideo Tanaka, Seiya Kikuchi
Rok vydání:	2015
Předmět:	Phosphine oxide chemistry.chemical_compound chemistry Magnesium Organic Chemistry Drug Discovery Inorganic chemistry chemistry.chemical_element Biochemistry Phosphine
Zdroj:	Tetrahedron Letters. 56:918-920
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2014.12.132
Popis:	Direct reductions of phosphine oxides to the corresponding phosphines were performed successfully by using Mg/Me3SiCl/DMI system. The reduction proceeded under mild conditions and was applicable to a wide range of phosphine oxides; triarylphosphine oxides, alkyldiarylphosphine oxides, and dialkylarylphosphine oxides gave the corresponding phosphines in good to excellent yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1eee2058b07bae7b73e6830f98cdca5d https://doi.org/10.1016/j.tetlet.2014.12.132 Zobrazit plný text záznamu Full Text from ScienceDirect