Crystal structure of [1,8-bis(quinoliniumoxy)-3,6-dioxaoctane·(H2O)2](BF4)2: hydrated quinolinium podand salt or hydronium ion complex?

Autor:	Steven J. Archer, Cheryl Sacht, Klaus R. Koch
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Bicyclic molecule Hydrogen bond Inorganic chemistry Intermolecular force Stacking Salt (chemistry) Crystal structure Inorganic Chemistry Crystallography chemistry Materials Chemistry Molecule Physical and Theoretical Chemistry Hydrate
Zdroj:	Inorganica Chimica Acta. 178:77-81
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(00)88137-2
Popis:	Structure of diprotonated, hydrated podand cation or hydronium ion complex? The title compound 2 represents the first example of a possible hydronium ion complex with an acyclic bis(quinolyl)- terminated oligoether. The molecule assumes a helical conformation, stabilized, in addition to intra- and intermolecular base stacking interactions, by two sets of bridging hydrogen bonds. The latter cannot unequivocally be formulated as either N···HOH2+ or NH+···OH2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1e9c111bb3198ec44f7ed551e4e86ee0 https://doi.org/10.1016/s0020-1693(00)88137-2 Zobrazit plný text záznamu