A Convenient Method for Preparing Aromatic Ketones from Acyl Chlorides and Arylboronic Acids via Suzuki—Miyaura Type Coupling Reaction

Autor:	Katsuyuki Ogura, Yoshio Urawa
Rok vydání:	2003
Předmět:	inorganic chemicals chemistry.chemical_compound Chemistry Aromatic ketones Organic chemistry General Medicine Hydrate Toluene Coupling reaction Catalysis
Zdroj:	ChemInform. 34
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200314100
Popis:	Aromatic ketones are synthesized efficiently via palladium-catalyzed cross-coupling reaction of boronic acids with acyl chlorides in the presence of K 3 PO 4 hydrate in toluene. This allows the use of aliphatic acyl chlorides as the starting material. Hydrated water plays a significant role as an H 2 O source to activate the catalytic system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1e9bff3b80bf3d57120175dfc4bf73e9 https://doi.org/10.1002/chin.200314100 Zobrazit plný text záznamu Plný text