Synthesis, spectrum and single crystal structure of a peroxovanadium complex of nitrilotriacetate ligand without water of crystallization, K2[VO(O2)NTA]

Autor:	Mei-Cheng Shao, Yong-Ge Wei, Shi-Wei Zhang, Gui-Qing Huang
Rok vydání:	1994
Předmět:	Tertiary amine Ligand Chemistry Inorganic chemistry Crystal structure Inorganic Chemistry Crystallography Pentagonal bipyramidal molecular geometry X-ray crystallography Materials Chemistry Molecule Water of crystallization Physical and Theoretical Chemistry Single crystal
Zdroj:	Polyhedron. 13:1587-1591
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(00)83454-3
Popis:	Crystals of the formula K2[VO(O2)NTA] with NTA = nitrilotriacetate have been prepared and characterized by IR and single-crystal X-ray diffraction methods. The structure of the anion of the complex shows that the vanadium atom has a distorted pentagonal bipyramidal environment surrounded by one oxo group, one peroxo group, three oxygen atoms and one nitrogen atom from the NTA ligand.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1e88ca128a7875ab857bc98c10f4fa6f https://doi.org/10.1016/s0277-5387(00)83454-3 Zobrazit plný text záznamu