Gas hydrate phase equilibria measurement techniques and phase rule considerations
| Autor: | Juan G. Beltran, Phillip Servio, Hallvard Bruusgaard |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
Chemistry
Clathrate hydrate Thermodynamics 02 engineering and technology 021001 nanoscience & nanotechnology Atomic and Molecular Physics and Optics symbols.namesake 020401 chemical engineering Carbon oxide Phase (matter) Phase rule symbols General Materials Science Physics::Chemical Physics 0204 chemical engineering Physical and Theoretical Chemistry 0210 nano-technology Hydrate Phase diagram |
| Zdroj: | The Journal of Chemical Thermodynamics. 44:1-4 |
| ISSN: | 0021-9614 |
| Popis: | A brief review of the Gibbs phase rule for non-reacting systems and its correct application to clathrate hydrates is presented. Clarification is provided for a common mistake found in hydrate phase-equilibria literature, whereby initial compositions are used as intensive variables to satisfy the Gibbs phase rule instead of the equilibrium values. The system of (methane + carbon dioxide + water) under (hydrate + liquid + vapor) equilibrium is used as a case study to illustrate key points and suggestions to improve experimental techniques are proposed. |
| Databáze: | OpenAIRE |
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