Enantioselective reduction of β-keto sulfones using the NaBH4/Me3SiCl system catalyzed by polymer-supported chiral sulfonamide

Autor:	Jian-bing Hu, Zhan-shan Qian, Wei-xing Yin, Gang Zhao
Rok vydání:	2002
Předmět:	Inorganic Chemistry chemistry.chemical_classification Chemistry Organic Chemistry Enantioselective synthesis Organic chemistry Physical and Theoretical Chemistry Medicinal chemistry Catalysis Polymer supported Sulfonamide
Zdroj:	Tetrahedron: Asymmetry. 13:2095-2098
ISSN:	0957-4166
DOI:	10.1016/s0957-4166(02)00546-3
Popis:	In the presence of 25 mol% of polymer-supported chiral sulfonamide, a variety of β-keto sulfones can be reduced into the corresponding β-hydroxy sulfones in excellent yields and with high enantioselectivities using the reducing system of NaBH 4 /Me 3 SiCl.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1e74806bb7aad1876f0524d4e790ecf9 https://doi.org/10.1016/s0957-4166(02)00546-3 Zobrazit plný text záznamu Full Text from ScienceDirect