ZnO-Al2O3-promoted CuO/ZrO2 catalyst prepared by oxalate gel-coprecipitation for the conversion of water-bearing materials

Autor: Gewen Yu, Jian Ding, Wenxiu He, Lan Dawei, Jiangang Chen, Yaxiong Wang, Juan Zhang, Zhou Chenliang
Rok vydání: 2017
Předmět:
Zdroj: Journal of Sol-Gel Science and Technology. 85:382-393
ISSN: 1573-4846
0928-0707
DOI: 10.1007/s10971-017-4542-5
Popis: Generally, ZrO2 facilitates the reactions of O-containing species, which result in the loss of activity or the sintering of Cu species via intimate interaction between water and CuO/ZrO2 catalysts. Indeed, the CuO/ZrO2 catalysts (CZo) prepared by oxalate gel-coprecipitation technique possessed a high dispersion of Cu and a certain degree of alkalinity. Unfortunately, it exhibited inferior catalytic activity in conversion of bio-ethanol (37.6% conversion). In contrast, the CuO–ZnO–Al2O3–ZrO2 catalysts (CZAZo) with extra addition of ZnO and Al2O3 showed a good catalytic performance and stability (>600 h on line). For example, the 92.5% selectivity of ethyl acetate based on 62.2% conversion of ethanol, was achieved. Besides, it performed better in hydrogenation of hydrous ethyl acetate than CZo. Evidently, the excellent performance in conversion of water-bearing materials was mainly due to the addition of ZnO and Al2O3 to CuO/ZrO2 catalysts. Besides, the uniform combination of each component could be achieved successfully by the employment of oxalate gel-coprecipitation. As a result, the surface electronic properties are tuned effectively and the affinity for water decreases sharply. Most importantly, the associated loss of active sites could be effectively avoided because of the reduced water coverage over CZAZo.
Databáze: OpenAIRE
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