Oxidative coupling of alkylbenzenes to diaryls catalyzed by the palladium(II)-heteropolyacid system

Autor: K. I. Matveev, G. U. Mennenga, A. I. Rudenkov, I. V. Kozhevnikov
Rok vydání: 1976
Předmět:
Zdroj: Reaction Kinetics and Catalysis Letters. 5:401-406
ISSN: 1588-2837
0133-1736
DOI: 10.1007/bf02060886
Popis: Oxidative coupling of alkylbenzenes (benzene, toluene, o-xylene, durene) is shown to proceed in the presence of palladium salts and heteropolyacids under the action of oxygen with a high yield of diaryls. The addition of mercury salts and variation of the solvent affect the reaction rate and isomer composition of the products.
Databáze: OpenAIRE