Oxidative coupling of alkylbenzenes to diaryls catalyzed by the palladium(II)-heteropolyacid system
Autor: | K. I. Matveev, G. U. Mennenga, A. I. Rudenkov, I. V. Kozhevnikov |
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Rok vydání: | 1976 |
Předmět: | |
Zdroj: | Reaction Kinetics and Catalysis Letters. 5:401-406 |
ISSN: | 1588-2837 0133-1736 |
DOI: | 10.1007/bf02060886 |
Popis: | Oxidative coupling of alkylbenzenes (benzene, toluene, o-xylene, durene) is shown to proceed in the presence of palladium salts and heteropolyacids under the action of oxygen with a high yield of diaryls. The addition of mercury salts and variation of the solvent affect the reaction rate and isomer composition of the products. |
Databáze: | OpenAIRE |
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