Solid-solution formation between arsenic and antimony oxides

Autor: Geoffrey Brooks, W. J. Rankin
Rok vydání: 1994
Předmět:
Zdroj: Metallurgical and Materials Transactions B. 25:865-871
ISSN: 1543-1916
1073-5615
DOI: 10.1007/bf02662768
Popis: An X-ray diffraction study of arsenic-trioxide and antimony-trioxide samples encapsulated under vacuum and then held at 395 °C for 24 hours revealed that cubic arsenic trioxide dissolves into cubic antimony trioxide up to a limit between 12.9 and 19.0 wt pct As. It was also found that arsenic trioxide does not dissolve as readily into antimony tetroxide, although the upper limit could not be determined by the technique used. These findings have implications in terms of their effect on proposed thermal techniques for separating arsenic and antimony oxides.
Databáze: OpenAIRE