An easy hydrothermal synthesis of porous CuS y Se 1-y nanomaterials with broadly tunable near-infrared localized surface plasmon resonance
Autor: | Minjian Yang, Qunwei Shu |
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Rok vydání: | 2016 |
Předmět: |
Materials science
Band gap Mechanical Engineering Metals and Alloys Nanotechnology 02 engineering and technology Photothermal therapy 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Nanomaterials Chalcogen Wavelength Mechanics of Materials Materials Chemistry Hydrothermal synthesis Surface plasmon resonance 0210 nano-technology Ternary operation |
Zdroj: | Journal of Alloys and Compounds. 660:361-369 |
ISSN: | 0925-8388 |
DOI: | 10.1016/j.jallcom.2015.11.074 |
Popis: | The ternary Cu 2-x S y Se 1-y nanomaterials have attracted great attention due to their unique optical properties, but they are primarily synthesized by the hot-injection and high temperature solvent method, however they are complex and uneconomical. In the paper, we report a new facile method for the synthesis of monodispersed and uniform porous CuS y Se 1-y alloyed nanomaterials with tunable composition, size, and morphology. More importantly, the near-infrared localized surface plasmon resonance (NIR LSPR) wavelength of these CuS y Se 1-y alloyed nanomaterials can be broadly tuned from 1027 to 1400 nm, and the energy bandgap can be simultaneously tuned from 1.42 to 1.91 eV by adjusting the chalcogen ratio. This approach opens up a new route to access to synthesize other porous ternary alloyed nanomaterials with broadly tunable LSPR wavelength and energy bandgap, which will find potential applications in the photothermal therapy and photovoltaic conversion. |
Databáze: | OpenAIRE |
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