A Comparative Study on Electrochemical Behavior of (La,Sr)FeO3 and (La,Sr)FeO3-(La,Sr)MnO3 Anodes for Solid Oxide Electrolysis Cells

Autor: Jing Ming Xu, Jing Wang, Wen Li Guo, Yong Zhang, Tong Xiang Liang, Chang Sheng Deng
Rok vydání: 2013
Předmět:
Zdroj: Applied Mechanics and Materials. 302:128-135
ISSN: 1662-7482
DOI: 10.4028/www.scientific.net/amm.302.128
Popis: La0.8Sr0.2FeO3 electrodes modified with nanoparticles of La0.8Sr0.2MnO3 (LSF/LSM) were prepared by infiltration method. LSM solution had good wettability on LSF surfaces and good electrochemical compatibility with LSF. The impedance of half-cells incorporating the electrodes was also examined. The deconvolution of the impedance spectrum indicated that the peak positions are changed after the LSF infiltration. The LSF/LSM electrode exhibited smaller polarization resistance than pure LSF electrode. Finally, a transform from asymmetry to symmetry appeared in the polarization curves of LSF/LSM electrode with the increase of temperature.
Databáze: OpenAIRE