Coordination polymers of CuII and NiII with 3-pyridin-3-yl-benzoate: crystal structures and magnetic properties

Autor:	Xiang-Yang Hou, Long Tang, Loujun Gao, Ya-Pan Wu, Feng Fu
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Thermogravimetric analysis Hydrogen bond Coordination polymer Supramolecular chemistry Stacking Infrared spectroscopy Polymer Crystal structure Crystallography chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Coordination Chemistry. 64:3136-3145
ISSN:	1029-0389 0095-8972
Popis:	Coordination polymers of CuII and NiII with 3-pyridin-3-yl-benzoic acid (3,3-Hpybz), {[Cu(3,3-pybz)2(CH3OH)]·(DMF)} n (1) and {[Ni(3,3-pybz)2(H2O)] · (H2O)} n (2), were synthesized and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, elemental analysis, and IR spectroscopy. In 1, CuII ions are linked by paired 3,3-pybz ligands to generate an infinite 1-D double-strand chain. However, NiII ions in 2 are linked by the 3,3-pybz to form a 2-D corrugated network with a simple (4,4) topology; these 2-D layers are further enlarged to form the final 3-D supramolecular edifice via strong aromatic π–π stacking interactions and O–H ··· O hydrogen bonds. Magnetic properties of 1 and 2 have also been investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1dfcfe06fdb8af300dc5dd40314529ba https://doi.org/10.1080/00958972.2011.614347 Zobrazit plný text záznamu