NMR investigation of complex formation between metalloporphyrins and ?-donors

Autor:	O. A. Chamaeva, A. N. Kitaigorodskii
Rok vydání:	1990
Předmět:	Hematoporphyrin chemistry.chemical_compound Anthracene Chloroform chemistry Phenanthroline Polymer chemistry Complex formation General Chemistry Photochemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1591-1595
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00961484
Popis:	The formation of molecular complexes between Co(II), Fe(III), and Mn(III) porphyrins and π-donors in chloroform solution has been investigated using1H NMR. It was shown that their stability is controlled to a large extent by the dimensions of the π-donor; interaction of the porphyrins with phenanthroline and anthracene, which contain a condensed aromatic system, is substantially more effective than interaction with benzene-derivative π-donors. In the case of Co(II) and Fe(III) porphyrins the affinity to it-acceptors is much more pronounced than the affinity to π-donors, whereas the acetate of Mn(III) hematoporphyrin forms molecular complexes with phenanthroline, anthracene, and trinitrobenzene with similar stability constants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1df0c6518a6afaf6a5457ec94c0880ed https://doi.org/10.1007/bf00961484 Zobrazit plný text záznamu Full text from SpringerLink