Popis: |
The use of laser radiation to locally modify nucleation barriers to thin film growth is discussed. Examples are described in which UV laser photodeposition is used to directly pattern surface-altering monolayer or submonolayer films. The surface-altering films can then be used to promote or both physical condensation as well as surface chmistry. A qualitative is made of two kinds of processes: those relying on physical, and those relying on chemical, barriers. A figure of merit is defined and discussed, which measures the selectivity of a given process for patterned growth. |