Synthesis and properties of liquid luminophores based on the POCl3-BiCl3-MCl x system

Autor:	G. V. Tikhonov, D. V. Kabakov, M. V. Zelenskaya
Rok vydání:	2009
Předmět:	Absorption spectroscopy Chemistry Excited state Yield (chemistry) Inorganic chemistry chemistry.chemical_element Qualitative inorganic analysis Lewis acids and bases Physical and Theoretical Chemistry Luminescence Neodymium Ion
Zdroj:	Radiochemistry. 51:250-255
ISSN:	1608-3288 1066-3622
Popis:	Stable BiCl3-containing solutions of phosphorus oxychloride, activated with UO22+ and Nd3+ ions, can be prepared only in the presence of another Lewis acid MClx. The electronic absorption spectra of the liquids prepared and the decay times of the Nd3+ luminescence are characteristic of individual solutions based on POCl3-MClx. The radiation-chemical yield of Nd3+ in the excited state 4F3/2 in POCl3-BiCl3-MClx-235UO22+-Nd3+ solutions upon homogeneous excitation with uranium α-particles is lower than in POCl3-MClx-235UO22+-Nd3+ solutions at comparable component concentrations. Apparently, Bi3+ in solutions based on the POCl3-BiCl3-MClx system is not incorporated in neodymium- and/or uranyl-containing complexes and remains in the matrix.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d9d13f35cd0b95002dd7b8557733d7a https://doi.org/10.1134/s1066362209030060 Zobrazit plný text záznamu Plný text ve formátu PDF