Synthesis, characterization and analytical applications of N-dodecyl pyridinium chloride-cerium (IV) phosphate fibrous ion exchanger: selective for Hg(II) and its binary separations

Autor:	Amita Somya, Md. Z. A. Rafiquee, K. G. Varshney, Hamad A. Al-Lohedan
Rok vydání:	2014
Předmět:	Thermogravimetric analysis Ion exchange Elution Metal ions in aqueous solution Inorganic chemistry chemistry.chemical_element Ocean Engineering Pollution Chloride Cerium chemistry.chemical_compound Adsorption chemistry medicine Pyridinium Water Science and Technology medicine.drug
Zdroj:	Desalination and Water Treatment. 56:638-645
ISSN:	1944-3986 1944-3994
Popis:	An intercalated hybrid fibrous ion exchanger has been synthesized by incorporating N-dodecyl pyridinium chloride with the inorganic cation exchanger, cerium (IV) phosphate. The synthesized, N-dodecyl pyridinium chloride-cerium (IV) phosphate (DPC-CeP) cation exchanger was characterized using X-ray diffraction studies, SEM, thermogravimeric (and differential thermogravimetric) analysis and elemental analysis. The ion-exchange characteristics (ion-exchange capacity, elution and concentration behaviour) and thermal stability were also determined by usual chemical method. The adsorption studies for alkaline earths and heavy metal ions on the synthesized material were also performed in different acidic media. DPC-CeP has been found to be selective for Hg(II) ions. Hence, some binary separations of Hg(II) ions from the mixture containing other metal ions have been carried out on its column, exploring the potential role of the synthesized material in environmental studies and water treatment.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d9a6cb5f5599bd1db5e769645daa2ca https://doi.org/10.1080/19443994.2014.940388 Zobrazit plný text záznamu