Paramagnetic absorption of pentavalent molybdenum in various symmetries of TiO2

Autor:	P. Meriaudeau, M. Che, G. Fichelle
Rok vydání:	1972
Předmět:	Anatase Chemistry Inorganic chemistry Spin–lattice relaxation General Physics and Astronomy chemistry.chemical_element Crystallography Paramagnetism Molybdenum Rutile Lattice (order) Homogeneous space Physical and Theoretical Chemistry Hyperfine structure
Zdroj:	Chemical Physics Letters. 17:66-69
ISSN:	0009-2614
DOI:	10.1016/0009-2614(72)80326-9
Popis:	Paramagnetic absorption of pentavalent molybdenum has been studied in TiO2 host lattice. The g was measured to be g∸ 1.917, g⊥ = 1.828 in anatase and gxx = 1.919, gyy = 1,822,gzz = 1.799 in rutile. The hyperfine tensor was measured to be A| = 7.4 × 10−3 cm−1, A⊥ not resolved in anatase and Axx = 6.5 × 10−3 cm−1, AYY = 2.5 × 10−3 cm−1, Azz = 3.2 × 10−3 cm−1 in ru tile. The spin lattice relaxation time was ≈10−9 sec in rutile.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d76bc26b07c94a5b2e743a3bf81dd65 https://doi.org/10.1016/0009-2614(72)80326-9 Zobrazit plný text záznamu