Mechanism of oxidation of cyclohexane by the radical cation of pyridine N-Oxide

Autor:	V. M. Berdnikov, S. N. Shamaev, S. I. Kulakovskaya
Rok vydání:	1990
Předmět:	chemistry.chemical_compound Radical ion chemistry Hydrogen Cyclohexane Pyridine chemistry.chemical_element Pyridine-N-oxide General Chemistry Cyclic voltammetry Photochemistry Acetonitrile Platinum
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 39:1345-1348
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00957834
Popis:	Oxidation of pyridine N-oxide in the presence of cyclohexane was studied on platinum and carbon glass rotating disk electrodes using the method of cyclic voltammetry in 0.2 N LiClO4 in acetonitrile. It was hypothesized that the electrochemically generated N-oxide radical cation reacts with cyclohexane according to the mechanism of hydrogen atom cleavage.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d6cdac73b06f775241f05bc6a33595d https://doi.org/10.1007/bf00957834 Zobrazit plný text záznamu Full text from SpringerLink