A novel integrated process for the functionalization of methane and ethane: bromine as mediator

Autor:	Peter C. Ford, Xiao-Ping Zhou, Galen D. Stucky, Dieter J. Schaefer, Leroy E. Laverman, Michael A. Weiss, Gurkan A. Yilmaz, Eric W. McFarland, Aysen Yilmaz, Shouli Sun, Ivan M. Lorkovic, Jeffrey H. Sherman, Maria L. Noy, C. Ian Cutler
Rok vydání:	2004
Předmět:	Alkane chemistry.chemical_classification Bromine Chemistry Oxide Halogenation chemistry.chemical_element General Chemistry Heterogeneous catalysis Catalysis chemistry.chemical_compound Bromide Organic chemistry Partial oxidation
Zdroj:	Catalysis Today. 98:317-322
ISSN:	0920-5861
DOI:	10.1016/j.cattod.2004.07.058
Popis:	We describe a novel, integrated multi-step process for the partial oxidation of alkanes to alcohols, ethers or olefins using O2 as oxidant. The sequential transformations are (1) alkane bromination to alkyl bromide(s) and HBr, (2) reaction of this mixture with solid metal oxide (MO) to neutralize the HBr and to generate oxygenated products or olefins plus solid metal bromide, and (3) oxidation of the spent solid with O2 to regenerate the metal oxide and Br2 for reuse.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d5895863b116c015efef5f2ed657091 https://doi.org/10.1016/j.cattod.2004.07.058 Zobrazit plný text záznamu Full Text from ScienceDirect