Double carbonylation of iodoarenes in the presence of a pyridinium SILP-Pd catalyst
| Autor: | Rita Skoda-Földes, Petra Nagy, Béla Urbán, Enikő Nagy, Máté Papp |
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| Rok vydání: | 2020 |
| Předmět: |
010405 organic chemistry
Organic Chemistry 010402 general chemistry 01 natural sciences Biochemistry Chloride 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound Aniline chemistry Nucleophile Phase (matter) Ionic liquid Polymer chemistry Materials Chemistry medicine Pyridinium Phosphonium Physical and Theoretical Chemistry medicine.drug |
| Zdroj: | Journal of Organometallic Chemistry. 918:121287 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2020.121287 |
| Popis: | The efficiency of a palladium catalyst, immobilised on a supported ionic liquid phase (SILP) with adsorbed 1-butyl-4-methylpyridinium chloride, was investigated in aminocarbonylation reactions. Double carbonylation was found to be the main reaction using different iodoarenes and aliphatic amines as substrates. Application of aniline derivatives as nucleophiles led to the exclusive formation of substituted benzamides. The stabilisation effect of the adsorbed pyridinium ionic liquid was compared to that of imidazolium and phosphonium derivatives. It was proved that the pyridinium SILP-palladium catalyst could be reused in at least 10 cycles. Recyclability was tested in five successive runs for all of the substrates. |
| Databáze: | OpenAIRE |
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