Models for unimolecular reactions in the solid phase and stability prediction of energetic compounds in the condensed state

Autor:	G. B. Manelis, G. M. Nazin, V. G. Prokudin
Rok vydání:	2011
Předmět:	Reaction rate constant Chemistry Phase (matter) Lattice defects Solid phases Physical chemistry Thermodynamics General Chemistry State (functional analysis) Crystal structure Stability (probability)
Zdroj:	Russian Chemical Bulletin. 60:1440-1447
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-011-0215-7
Popis:	The results of analysis and refinement of phenomenological models for unimolecular reactions proceeding homogeneously in the bulk of undistorted crystal lattice or localized on the lattice defects are presented. It is shown that, within the framework of these models, the ratio of the rate constants for reactions in the liquid and solid phases, K = kl/ks, can be calculated with satisfactory accuracy and thus the known kl values can be used to predict the rate constant ks characterizing the stability of the materials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d39beff506d27447e7ef5b8c232f538 https://doi.org/10.1007/s11172-011-0215-7 Zobrazit plný text záznamu Full text from SpringerLink