Organometallic chemistry of bis(N-heterocyclic carbene) ligands containing a heteroarene spacer
| Autor: | Wanzhi Chen, Shixian Zhao, Junshi Wu |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Phenanthroline Transition metal carbene complex Organic Chemistry Homogeneous catalysis 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Bipyridine chemistry Polymer chemistry Materials Chemistry Metal–ligand multiple bond Organic chemistry Transition metal thiolate complex Physical and Theoretical Chemistry Carbene Organometallic chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 848:249-280 |
| ISSN: | 0022-328X |
| Popis: | Heteroarene-linked bis(N-heterocyclic carbenes) constitute an important family of ligands in transition metal chemistry and homogeneous catalysis. These ligands are used as multidentate ligands for the construction of mononuclear and multinuclear complexes that show unique physical properties and that are efficient catalysts for many organic transformations. A number of transition metal complexes of heteroarene-linked bis(N-heterocyclic carbene) ligands have been synthesized and structurally characterized in recent decades. In this review, we summarize the recent developments in metal complexes supported by heteroarene-linked bis(N-heterocyclic carbene) ligands and their applications. The ligands and their complexes are categorized by the linkers between the two NHCs, such as pyridine, bipyridine, phenanthroline, naphthyridine, pyrazole, thiophene, and pyridazine. |
| Databáze: | OpenAIRE |
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