35Cl NQR of the benzene sulphonyl chlorides

Autor:	D.J. Pusiol, A.H. Brunetti
Rok vydání:	1983
Předmět:	Stereochemistry Organic Chemistry Resonance chemistry.chemical_element Atmospheric temperature range Chloride Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Chlorobenzene Chlorine medicine Molecule Solid phases Benzene Spectroscopy medicine.drug
Zdroj:	Journal of Molecular Structure. 96:293-300
ISSN:	0022-2860
DOI:	10.1016/0022-2860(83)90057-1
Popis:	The NQR frequencies of p -chlorobenzene sulphonyl chloride are investigated in the temperature range 100–240 K. Two solid phases have been found in this compound for both of which two resonances have been observed throughout the temperature range, corresponding to the two chemically inequivalent chlorine sites in the molecule. Analysis of the temperature dependence of the NQR frequency difference between two phases and the two sites in the molecule reveals the influence on the NQR frequencies of semi-external molecular motion involving the CS bond at certain triggering temperatures found throughout the temperature range 130–180 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1d331520db53aa0ccf8f9052b08a0fd0 https://doi.org/10.1016/0022-2860(83)90057-1 Zobrazit plný text záznamu