Dynamic characteristics of molecules, grafted to a silica surface

Autor: V. B. Golubev, V. V. Matveev, S. M. Staroverov, G. V. Lisichkin
Rok vydání: 1988
Předmět:
Zdroj: Theoretical and Experimental Chemistry. 24:670-675
ISSN: 1573-935X
0040-5760
DOI: 10.1007/bf00531360
Popis: The mobility of nitroxyl radicals, grafted to silica, depends essentially on the method of attachment to the surface, the composition of the medium, and the temperature. The presence in the grafted molecules of functional groups, interacting with the silanol groups, reduces significantly the mobility of the attached molecules. The transition from hydrocarbons to polar solvents noticeably increases the mobility of the grafted groups.
Databáze: OpenAIRE