Dynamic characteristics of molecules, grafted to a silica surface
Autor: | V. B. Golubev, V. V. Matveev, S. M. Staroverov, G. V. Lisichkin |
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Rok vydání: | 1988 |
Předmět: | |
Zdroj: | Theoretical and Experimental Chemistry. 24:670-675 |
ISSN: | 1573-935X 0040-5760 |
DOI: | 10.1007/bf00531360 |
Popis: | The mobility of nitroxyl radicals, grafted to silica, depends essentially on the method of attachment to the surface, the composition of the medium, and the temperature. The presence in the grafted molecules of functional groups, interacting with the silanol groups, reduces significantly the mobility of the attached molecules. The transition from hydrocarbons to polar solvents noticeably increases the mobility of the grafted groups. |
Databáze: | OpenAIRE |
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