ChemInform Abstract: Base-Induced Photorearrangements from 3-Styrylfurans to 2-Methylnaphthalenes

Autor:	Chia-Kai Lo, Jinn-Hsuan Ho, Chao-Li Chuang, Tunng-Hsien Lee
Rok vydání:	2012
Předmět:	Photoisomerization Chemistry General Medicine Base (exponentiation) Medicinal chemistry Isopropyl
Zdroj:	ChemInform. 43
ISSN:	0931-7597
DOI:	10.1002/chin.201215081
Popis:	Irradiation of 3-(4-substituted styryl)furans in basic media yielded a series of 7-substituted-2-methylnaphthalenes, including methoxy, isopropyl, ethyl, methyl, fluoro, and cyano substituents. This base-induced photorearrangement involves cis–trans photoisomerization, 6e photocyclization, base-induced elimination, and a Norrish Type I photoreaction and is a novel method to synthesize unsymmetrical 2,7-disubstituted naphthalenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1ce062e8e8f4e48613b4a18d80c14f10 https://doi.org/10.1002/chin.201215081 Zobrazit plný text záznamu Plný text