14C-Labeled Alcohol Tracer Study: Comparison of Reactivity of Alcohols over Cobalt and Ruthenium Fischer–Tropsch Catalysts

Autor:	Wilson D. Shafer, Arno de Klerk, Muthu Kumaran Gnanamani, Debanjan Chakrabarti, Robert A. Keogh, Burtron H. Davis, Dennis E. Sparks, Venkat Ramana Rao Pendyala
Rok vydání:	2015
Předmět:	Chemistry Inorganic chemistry Decarbonylation chemistry.chemical_element Fischer–Tropsch process Alcohol General Chemistry Catalysis Ruthenium chemistry.chemical_compound Reactivity (chemistry) Methanol Cobalt
Zdroj:	Topics in Catalysis. 58:343-349
ISSN:	1572-9028 1022-5528
Popis:	The reactivity of 14C-labeled ethanol (CH 3 14 CH2OH) and 1-propanol (CH3CH 2 14 CH2OH) added during Fischer–Tropsch synthesis (FTS) was studied in a continuous-flow well-stirred reactor operated at 220 °C and 18.7 atm using a supported cobalt or ruthenium catalyst. The added labeled alcohols are mostly found in the product gas and water phase (≥99 %) without being involved in any reaction over both fcc and hcp metallic cobalt. The data indicate that C–O bond of ethanol and 1-propanol remains mostly stable on cobalt under FTS conditions. However, 1-propanol is likely to be involved in a chain initiation after decarbonylation apart from being degraded into methanol on ruthenium.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1cdd2c82f32d39360f091bfa72bb78b7 https://doi.org/10.1007/s11244-015-0375-z Zobrazit plný text záznamu Plný text ve formátu PDF