The crystal and molecular structure of triamminetriaquocobalt(III) perchlorate, [Co(NH3)3(H2O)3](ClO4)3. A highly disordered structure

Autor:	Thomas F. Brennan, Alfred R. Garafalo, A. P. Gardner, G. C. Davies
Rok vydání:	1978
Předmět:	Structure (category theory) chemistry.chemical_element Zonal and meridional Center (group theory) Inorganic Chemistry Crystal Perchlorate chemistry.chemical_compound Crystallography chemistry Group (periodic table) Materials Chemistry Molecule Physical and Theoretical Chemistry Cobalt
Zdroj:	Inorganica Chimica Acta. 30:97-101
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(00)89021-0
Popis:	The structure of triamminetriaquocobalt(III) perchlorate has been determined by the Patterson method. It crystallizes in the cubic space group Pm3 with a unit cell dimengon of a = 11.213(2) A . The structure was refined to final weighted and unweighted R factors of 0.062 and 0.082, respectively. The two independent cobalt centers were found to exhibit different degrees of disorder. One center appears to have a meridional distribution of ligands while it is not possible to determine whether the distribution about the second cobalt center is meridional or facial. The three independent perchlorate groups are also disordered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1cd2bc59a6c13b617ba5be758a232681 https://doi.org/10.1016/s0020-1693(00)89021-0 Zobrazit plný text záznamu