Investigation of the vibrational spectra of certain organosilicon acetylenic and diacetylenic compounds

Autor: M. F. Shostakovskii, I. I. Igonina, E.I. Brodskaya, N. I. Shergina, N. V. Komarov
Rok vydání: 1964
Předmět:
Zdroj: Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 13:1046-1048
ISSN: 1573-9171
0568-5230
Popis: 1. The IR spectra of six silicon-acetylenic compounds, synthesized for the first time, were studied, and the integral intensities of the triple bonds were measured according to the Raman spectra. 2. The introduction of various substituents into the molecules of the indicated compounds has no significant influence on the position of the absorption bands of the triple bond situated in the α-position to the silicon atom. At the same time, the integral intensities of the triple bonds depend both on the character of the α-substituent and on the organic radicals bonded to the silicon.
Databáze: OpenAIRE