Crosslinking of epoxidized natural oils with diepoxy reactive diluents
| Autor: | Jolita Ostrauskaite, Emmanuelle-Anita-Claude Demengeot, Juozas V. Grazulevicius, Inga Baliutaviciene, Violeta Grazuleviciene, Lina Rageliene, L. Augulis |
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| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis Materials science Diglycidyl ether Polymers and Plastics Cationic polymerization General Chemistry Polymer engineering.material Biodegradation Diluent Surfaces Coatings and Films chemistry.chemical_compound chemistry Materials Chemistry engineering Organic chemistry Biopolymer Cellulose |
| Zdroj: | Journal of Applied Polymer Science. 115:2028-2038 |
| ISSN: | 1097-4628 0021-8995 |
| DOI: | 10.1002/app.31347 |
| Popis: | The different natural oils epoxidized with 3-chloroperbenzoic acid were crosslinked with diepoxy reactive diluents, bisphenol A propoxylate diglycidyl ether, and 3,4-epoxycyclohexylmethyl-3,4-epoxyclohexane-carboxylate, using cationic initiator at 60°C and photoinitiators at the room temperature. The insoluble fraction of the polymeric products was 59–90%. The Young modulus of the crosslinked polymer films ranged from 2 to 861 MPa. The 10% weight loss temperatures of the crosslinked polymers estimated by thermogravimetric analysis were in the range from 250 to 420°C. The water vapor transmission rate of the crosslinked biopolymer films ranged from 6 to 49 g/m2/24 h. Biochemical oxygen demand and biodegradation in soil of the crosslinked polymers were studied. The crosslinked polymers showed higher biodegradation rate than cellulose, starch, and polyvinylalcohol. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 |
| Databáze: | OpenAIRE |
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