ChemInform Abstract: Stereoselective Syntheses of Isomers of 3,7-Dimethylnonadecane, a Sex Pheromone of the Alfalfa Blotch Leafminer (Agromyza frontella (Rondani) )

Autor:	François Bilodeau, Robert H. Burnell, David O. Miller
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Sex pheromone Pheromone Stereoselectivity General Medicine Agromyza frontella Pulegone Terpenoid Stereocenter
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199149293
Popis:	Two related stereoselective syntheses of 3,7-dimethylnonadecane, a sex pheromone of the alfalfa leafminer, are described to show that pulegone can serve as a useful starting material for the preparation of chiral aliphatic isoprenoid compounds. The schemes are designed to place the stereogenic center of pulegone at C.3 in one synthesis and at C.7 in the other so that the optical properties of the products can be compared with one another and with the values calculated using Brewster's rules. Key words: chiral hydrocarbons, stereoselective synthesis, pheromone, Agromyza frontella.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1caa65002d92926037161913589fd1c4 https://doi.org/10.1002/chin.199149293 Zobrazit plný text záznamu Plný text